Thermochemistry of Copper(II) β-Diketonates, II. Bis(benzoylacetonato)copper(II)
نویسندگان
چکیده
منابع مشابه
Mass Spectrometric Study of Copper(II) β-Diketonates Vapour Thermolysis Mechanism and Kinetics
Vapour thermolysis processes of copper(I1) bis-chelate complexes with different p-diketones in the 160640°C temperature range were studied by using the high-temperature source of a molecular beam with mass spectrometric recording of the gas phase composition directly at the outlet from the thermal reactor. Schemes of a heterogeneous decomposition of these compounds vapour were suggested on the ...
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Difluoroboron β-diketonates have impressive optical properties in both solution and the solid state. In particular, both fluorescence and room-temperature phosphorescence are present when the dyes are confined to a rigid matrix, such as poly(lactic acid) (PLA). To expand current knowledge and color range capabilities of this unique type of multi-emitting chromophore, a series of thienyl-substit...
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Four novel ruthenium organometallic complexes: [(η⁶-p-cymene)Ru(4,4,4-trifluoro-1-(4-bromophenyl)-1,3-butanedione)Cl] (1), [(η⁶-p-cymene)Ru(4,4,4-trifluoro-1-(4-bromophenyl)-1,3-butanedione)pta]PF₆ (2), [(η⁶-p-cymene)Ru(4,4,4-trifluoro-1-(4-iodophenyl)-1,3-butanedione)Cl] (3) and [(η⁶-p-cymene)Ru(4,4,4-trifluoro-1-(4-iodophenyl)-1,3-butanedione)pta]PF₆ (4) were synthesized and characterized by ...
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A new concept for the structural design of valence tautomeric (VT) metal complexes involving the formation of stable adducts of a tetracoordinate transition metal complex with a suitable bidentate redox-active ligand has been computationally studied using the DFT B3LYP*/6-311++G(d,p) method. The calculations, performed on a series of adducts of Co(II) diketonates with o-benzoquinone and its mon...
متن کاملComments on Intermetallic Thermochemistry
The need of a concerted multi-disciplinary approach in the investigation of intermetallic systems and the role of thermochemistry are underlined. The activity carried out in the Author’s laboratory in the alloy thermodynamics is summarized. The different instruments (calorimeters) built in laboratory are briefly presented and their performance discussed. The results obtained in the measurement ...
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ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1979
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.52.3080